CLEARING THE AIR
Lamont’s Decarbonization Technologies Take a Giant Step Forward
Carbon dioxide (CO2) levels today are higher than at any point in the past 800,000 years or more.
During a year when terms like carbon neutrality and net zero have become more and more commonly used, it appears the world is waking up to the imperative underscored in every high-level climate assessment—humanity needs to make a drastic change to stem the most catastrophic climate change consequences.
Climate impacts are happening more quickly than many scientists had predicted. Greenhouse gases are making the planet hotter. That rise in temperature is disrupting the weather and climate system in profound and cascading ways. For example, the western United States’ unprecedented drought has set up this region for devastating consecutive fire seasons. The rise in temperature triggers the air to hold more moisture, creating conditions for record breaking rainfall in the northeast, intensifying hurricanes, flooding neighborhoods, and threatening communities. The warmer temperature is also disrupting food webs. In the Arabian Sea, a strangely resilient and previously rare plankton species has ravaged the fishing industry.
In its 2020 report, The UN Environmental Programme (UNEP) concluded that despite a slight dip in atmospheric CO2 created by the pandemic lock down in 2019, “the world is still heading for a catastrophic temperature rise in excess of 3°C this century—far beyond the Paris Agreement goals of limiting global warming to well below 2°C and pursuing 1.5°C.” It goes on to say, to avoid the worst consequences of global warming, we need to remove ten billion tons of CO2 from the air by 2050.
In other words, in addition to drastically cutting global fossil fuel emissions, society needs to develop and use technologies to remove the CO2 already in the atmosphere. This is a huge undertaking, but one that scientists at Lamont-Doherty Earth Observatory have been striving towards for more than a decade.
Decarbonization, the process of capturing CO2 from the air and from industrial processes, has been in various stages of development at Lamont-Doherty for several years. One of many strategies that researchers are developing involves harnessing a natural process by which the Earth itself takes back CO2 from the air, and CO2 generated by power production.
Geologist Peter B. Kelemen is a research scientist at Lamont-Doherty Earth Observatory and the Arthur D. Storke Memorial Professor in the Department of Earth and Environmental Sciences. He has been a key architect of the Oman Drilling Project, an initiative involving more than 200 international scientists from disciplines such as geophysics, geochemistry, geology, biology, and physics who are working on research topics related to a unique geological feature in the Oman desert. In this region, the oceanic crust and its underlying mantle rocks have been thrust up onto the surface, creating the largest on-land exposure of ocean crust and upper mantle in the world.
Atmospheric CO2 spontaneously reacts with rocks from the Earth’s interior, the mantle, to form “carbonate” minerals, both removing CO2 from air, and permanently storing it in solid form. This is driven by the chemical energy due to disequilibrium between mantle rocks and the atmosphere.
“We wanted to figure out the cheapest way to take carbon dioxide out of the air and we came up with something very simple. Take limestone, cook it. Now you have CO2, to store or use, and calcium oxide. Put the CaO out in the weather. It will draw down CO2 from air, to make limestone again. Repeat. This is so simple, it is almost stupid. But we are finding that we can convert 75% of CaO to limestone in less than two weeks, just reacting with air in the lab. And, because the process is so simple, it currently has the lowest peer-reviewed cost estimate, of any proposed method for Direct Air Capture.”
PETER KELEMEN
Arthur D. Storke Memorial Professor, Department of Earth and Environmental Sciences, Geochemistry, Lamont-Doherty Earth Observatory, Columbia Climate School
Kelemen studies the chemical and physical processes of reaction between fluids and rocks. Kelemen’s primary focus now is on CO2 removal from air and permanent storage via engineered methods that emulate natural carbon mineralization. While his work in this area began in 2006, during fiscal year 2020, his discoveries have begun to fuel exciting industry investment and commercialization. First came a major innovation.
Kelemen and co-workers have developed several patents for processes that harness this naturally available chemical energy to yield low cost CO2 removal from air and geological storage.
“We wanted to figure out the cheapest way to take carbon dioxide out of the air and we came up with something very simple. Take limestone, cook it. Now you have CO2, to store or use, and calcium oxide. Put the CaO out in the weather. It will draw down CO2 from air, to make limestone again. Repeat. This is so simple, it is almost stupid. But we are finding that we can convert 75 percent of CaO to limestone in less than two weeks, just reacting with air in the lab. And, because the process is so simple, it currently has the lowest peer-reviewed cost estimate, of any proposed method for Direct Air Capture.”
Two start-up companies are putting Kelemen’s innovation to work. Heirloom Carbon Technologies based in California is committed to removing one billion tons of CO2 from the air by 2035 by “looping” CaO and CaCO3 as described above.
Meanwhile, 4401.Earth based in Oman is focusing on storage of CO2 removed from air, by forming solid carbonate minerals below the surface.
Both represent a profound advancement in the practical application of decarbonization science.
“It’s the most promising I’ve seen so far. And so it’s very gratifying to finally see these things moving toward tests on the field scale,“ said Kelemen.
Gamer Changer:
Off-Shore
Decarbonization
CLEARING
THE AIR
Lamont’s Decarbonization Technologies Take a Giant Step Forward
Carbon dioxide (CO2) levels today are higher than at any point in the past 800,000 years or more.
During a year when terms like carbon neutrality and net zero have become more and more commonly used, it appears the world is waking up to the imperative underscored in every high-level climate assessment—humanity needs to make a drastic change to stem the most catastrophic climate change consequences.
Climate impacts are happening more quickly than many scientists had predicted. Greenhouse gases are making the planet hotter. That rise in temperature is disrupting the weather and climate system in profound and cascading ways. For example, the western United States’ unprecedented drought has set up this region for devastating consecutive fire seasons. The rise in temperature triggers the air to hold more moisture, creating conditions for record breaking rainfall in the northeast, intensifying hurricanes, flooding neighborhoods, and threatening communities. The warmer temperature is also disrupting food webs. In the Arabian Sea, a strangely resilient and previously rare plankton species has ravaged the fishing industry.
Carbon dioxide (CO2) levels today are higher than at any point in the past 800,000 years or more.
During a year when terms like carbon neutrality and net zero have become more and more commonly used, it appears the world is waking up to the imperative underscored in every high-level climate assessment—humanity needs to make a drastic change to stem the most catastrophic climate change consequences.
Climate impacts are happening more quickly than many scientists had predicted. Greenhouse gases are making the planet hotter. That rise in temperature is disrupting the weather and climate system in profound and cascading ways. For example, the western United States’ unprecedented drought has set up this region for devastating consecutive fire seasons. The rise in temperature triggers the air to hold more moisture, creating conditions for record breaking rainfall in the northeast, intensifying hurricanes, flooding neighborhoods, and threatening communities. The warmer temperature is also disrupting food webs. In the Arabian Sea, a strangely resilient and previously rare plankton species has ravaged the fishing industry.
In its 2020 report, The UN Environmental Programme (UNEP) concluded that despite a slight dip in atmospheric CO2 created by the pandemic lock down in 2019, “the world is still heading for a catastrophic temperature rise in excess of 3°C this century—far beyond the Paris Agreement goals of limiting global warming to well below 2°C and pursuing 1.5°C.” It goes on to say, to avoid the worst consequences of global warming, we need to remove ten billion tons of CO2 from the air by 2050.
In other words, in addition to drastically cutting global fossil fuel emissions, society needs to develop and use technologies to remove the CO2 already in the atmosphere. This is a huge undertaking, but one that scientists at Lamont-Doherty Earth Observatory have been striving towards for more than a decade.
Decarbonization, the process of capturing CO2 from the air and from industrial processes, has been in various stages of development at Lamont-Doherty for several years. One of many strategies that researchers are developing involves harnessing a natural process by which the Earth itself takes back CO2 from the air, and CO2 generated by power production.
Geologist Peter B. Kelemen is a research scientist at Lamont-Doherty Earth Observatory and the Arthur D. Storke Memorial Professor in the Department of Earth and Environmental Sciences. He has been a key architect of the Oman Drilling Project, an initiative involving more than 200 international scientists from disciplines such as geophysics, geochemistry, geology, biology, and physics who are working on research topics related to a unique geological feature in the Oman desert. In this region, the oceanic crust and its underlying mantle rocks have been thrust up onto the surface, creating the largest on-land exposure of ocean crust and upper mantle in the world.
Atmospheric CO2 spontaneously reacts with rocks from the Earth’s interior, the mantle, to form “carbonate” minerals, both removing CO2 from air, and permanently storing it in solid form. This is driven by the chemical energy due to disequilibrium between mantle rocks and the atmosphere.
“We wanted to figure out the cheapest way to take carbon dioxide out of the air and we came up with something very simple. Take limestone, cook it. Now you have CO2, to store or use, and calcium oxide. Put the CaO out in the weather. It will draw down CO2 from air, to make limestone again. Repeat. This is so simple, it is almost stupid. But we are finding that we can convert 75% of CaO to limestone in less than two weeks, just reacting with air in the lab. And, because the process is so simple, it currently has the lowest peer-reviewed cost estimate, of any proposed method for Direct Air Capture.”
PETER KELEMEN
Arthur D. Storke Memorial Professor, Department of Earth and Environmental Sciences, Geochemistry, Lamont-Doherty Earth Observatory, Columbia Climate School
Kelemen studies the chemical and physical processes of reaction between fluids and rocks. Kelemen’s primary focus now is on CO2 removal from air and permanent storage via engineered methods that emulate natural carbon mineralization. While his work in this area began in 2006, during fiscal year 2020, his discoveries have begun to fuel exciting industry investment and commercialization. First came a major innovation.
Kelemen and co-workers have developed several patents for processes that harness this naturally available chemical energy to yield low cost CO2 removal from air and geological storage.
“We wanted to figure out the cheapest way to take carbon dioxide out of the air and we came up with something very simple. Take limestone, cook it. Now you have CO2, to store or use, and calcium oxide. Put the CaO out in the weather. It will draw down CO2 from air, to make limestone again. Repeat. This is so simple, it is almost stupid. But we are finding that we can convert 75 percent of CaO to limestone in less than two weeks, just reacting with air in the lab. And, because the process is so simple, it currently has the lowest peer-reviewed cost estimate, of any proposed method for Direct Air Capture.”
Two start-up companies are putting Kelemen’s innovation to work. Heirloom Carbon Technologies based in California is committed to removing one billion tons of CO2 from the air by 2035 by “looping” CaO and CaCO3 as described above.
Meanwhile, 4401.Earth based in Oman is focusing on the storage of CO2 removed from air, by forming solid carbonate minerals below the surface.
Both represent a profound advancement in the practical application of decarbonization science.
“It’s the most promising I’ve seen so far. And so it’s very gratifying to finally see these things moving toward tests on the field scale,“ said Kelemen.
Gamer Changer:
Off-Shore Decarbonization
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Writer/Editor: Marie DeNoia Aronsohn I Contributing Editors: Tara Spinelli and Marian Mellin I Contributing Writer: John Palmer I Design: Carmen Neal
Columbia Climate School Lamont-Doherty Earth Observatory Annual Report FY2021
© 2021 by The Trustees of Columbia University in the City of New York, Lamont-Doherty Earth Observatory. All rights reserved.
Writer/Editor: Marie DeNoia Aronsohn
Contributing Editors: Tara Spinelli and Marian Mellin
Contributing Writer: John Palmer
Design: Carmen Neal
Columbia Climate School Lamont-Doherty Earth Observatory Annual Report FY2021
© 2021 by The Trustees of Columbia University in the City of New York, Lamont-Doherty Earth Observatory. All rights reserved.